Self-healing and shape-memory polymers based on cellulose acetate matrix
Abstrak
The creation of self-healing polymers with superior strength and stretchability from biodegradable materials is attracting increasing attention. In this study, we synthesized new biomass-derived cellulose acetate (CA) derivatives by ring-opening graft polymerization of δ-valerolactone followed by the introduction of ureidopyrimidinone (Upy) groups in the polymer side chains. Due to the semicrystalline aliphatic characteristics of the side chain poly(δ-valerolactone) (PVL) and quadruple hydrogen bonds formed by the Upy groups, the stretchability of the resulting polymers was significantly enhanced. Moreover, the shape memory ability and self-healing property (58.3% of self-healing efficiency) were successfully imparted to the polymer. This study demonstrates the great significance of using biomass sources to create self-healing polymers.
Topik & Kata Kunci
Penulis (5)
Han Jia
Keiya Jimbo
Hirogi Yokochi
Hideyuki Otsuka
Tsuyoshi Michinobu
Akses Cepat
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Cek di sumber asli →- Tahun Terbit
- 2024
- Sumber Database
- DOAJ
- DOI
- 10.1080/14686996.2024.2320082
- Akses
- Open Access ✓