DOAJ Open Access 2019

Thermodynamic description of alkali metal hydroxides over a wide range of temperatures, pressures and densities of aqueous fluids

Akinfiev Nikolay

Abstrak

All available experimental data on dissociation constants of aqueous hydroxides of Na, K, and Li were critically assembled and together with quantum chemical estimations used to evaluate parameters of the AD EoS [1] for corresponding aqueous molecules NaOH(aq), KOH(aq), and LiOH(aq). Use of the proposed approach allows proper prediction of the whole set of thermodynamic properties of these hydroxides over a wide range of temperatures (0 – 800 °C), pressures (0.1 – 800 MPa) and solvent densities (0.03 – 1.1 g·cm-3).

Topik & Kata Kunci

Penulis (1)

A

Akinfiev Nikolay

Format Sitasi

Nikolay, A. (2019). Thermodynamic description of alkali metal hydroxides over a wide range of temperatures, pressures and densities of aqueous fluids. https://doi.org/10.1051/e3sconf/20199805001

Akses Cepat

Lihat di Sumber doi.org/10.1051/e3sconf/20199805001
Informasi Jurnal
Tahun Terbit
2019
Sumber Database
DOAJ
DOI
10.1051/e3sconf/20199805001
Akses
Open Access ✓