DOAJ Open Access 2025

Large-scale alkali-assisted growth of monolayer and bilayer WSe2 with a low defect density

Sui-An Chou Chen Chang Bo-Hong Wu Chih-Piao Chuu Pai-Chia Kuo +12 lainnya

Abstrak

Abstract The development of p-type WSe2 transistors has lagged behind n-type MoS2 because of challenges in growing high-quality, large-area WSe2 films. This study employs an alkali-assisted CVD (AACVD) method by using KOH to enhance nucleation on sapphire substrates, effectively promoting monolayer growth on c-plane sapphire and enabling controlled bilayer seeding on miscut surfaces with artificial steps. With AACVD, we achieve 2-inch monolayer and centimeter-scale bilayer WSe2 films with defect densities as low as 1.6 × 1012 cm−2 (monolayer) and 1.8 × 1012 cm−2 (bilayer), comparable to exfoliated WSe2. Bilayer WSe2 transistors exhibit hole/electron mobilities of 119/34 cm²/Vs, while monolayers achieve 105/22 cm²/Vs with suitable metal contacts. Additionally, bilayer WSe2 demonstrates lower contact resistance for both n-type and p-type transistors, making it highly promising for future high-performance electronic applications.

Topik & Kata Kunci

Penulis (17)

S

Sui-An Chou

C

Chen Chang

B

Bo-Hong Wu

C

Chih-Piao Chuu

P

Pai-Chia Kuo

L

Liang-Hsuan Pan

K

Kai-Chun Huang

M

Man-Hong Lai

Y

Yi-Feng Chen

C

Che-Lun Lee

H

Hao-Yu Chen

J

Jessie Shiue

Y

Yu-Ming Chang

M

Ming-Yang Li

Y

Ya-Ping Chiu

C

Chun-Wei Chen

P

Po-Hsun Ho

Format Sitasi

Chou, S., Chang, C., Wu, B., Chuu, C., Kuo, P., Pan, L. et al. (2025). Large-scale alkali-assisted growth of monolayer and bilayer WSe2 with a low defect density. https://doi.org/10.1038/s41467-025-57986-1

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Informasi Jurnal
Tahun Terbit
2025
Sumber Database
DOAJ
DOI
10.1038/s41467-025-57986-1
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Open Access ✓