DOAJ Open Access 2022

Enhancing aromatic yield from catalytic pyrolysis of Ca2+-loaded lignin coupled with metal-modified HZSM-5

Huiyan Zhang Bingbing Luo Kai Wu Han Wu Jiajun Yu +1 lainnya

Abstrak

Catalytic fast pyrolysis of lignin is easy to cause agglomeration and coking, resulting in low-yield aromatic hydrocarbons. Catalytic pyrolysis of modified lignin combined with metal-modified HZSM-5 was proposed to enhance the aromatic yield. The experiment results showed that chemical modification with Ca(OH)2 not only inhibited the agglomeration behavior of lignin but also increased the yield of light phenolic compounds. Moreover, Ca2+-loaded lignin combined with metal-modified HZSM-5 was conducive to the formation of aromatics. The total yield of aromatics from the catalytic fast pyrolysis of Ca2+-loaded lignin over Zn/HZSM-5 was improved from 31.1 to 46.1 mg/g. The mechanism insight showed that Ca2+ modification realized the chemical combination between Ca2+ and the functional groups which are responsible for the agglomeration of lignin, and then the introduction of the Zn species suppressed the hydrogen transfer reaction and enhanced the dehydrogenation pathway, resulting in the increase of aromatic yield.

Topik & Kata Kunci

Fuel Energy industries. Energy policy. Fuel trade

Penulis (6)

Huiyan Zhang

Bingbing Luo

Kai Wu

Han Wu

Jiajun Yu

Siyu Wang

Format Sitasi

APA MLA BibTeX

Zhang, H., Luo, B., Wu, K., Wu, H., Yu, J., Wang, S. (2022). Enhancing aromatic yield from catalytic pyrolysis of Ca2+-loaded lignin coupled with metal-modified HZSM-5. https://doi.org/10.1016/j.jaecs.2021.100049

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Informasi Jurnal

Tahun Terbit: 2022
Sumber Database: DOAJ
DOI: 10.1016/j.jaecs.2021.100049
Akses: Open Access ✓