DOAJ Open Access 2022

Dual-ionic imidazolium salts to promote synthesis of cyclic carbonates at atmospheric pressure

Tengfei Wang Danning Zheng Beibei An Yi Liu Tiegang Ren +4 lainnya

Abstrak

Novel dual-ionic imidazolium salts are shown to display excellent catalytic activity for cycloaddition of carbon dioxide and epoxides under room temperature and atmospheric pressure (0.1 MPa) without any solvent and co-catalyst leading to 96.1% product yield. It can be reused five times to keep the product yield over 90%. These intriguing results are attributed to a new reaction mechanism, which is supported by theoretical calculations along with the measurements of 13C NMR spectrum and Fourier transform infrared spectroscopy (FT-IR). The excellent catalytic activity can be traced to a CO2-philic group along with an electrophilic hydrogen atom. Our work shows that incorporation of CO2-philic group is an feasible pathway to develop the new efficient ionic liquids.

Topik & Kata Kunci

Renewable energy sources Ecology

Penulis (9)

Tengfei Wang

Danning Zheng

Beibei An

Yi Liu

Tiegang Ren

Hans Ågren

Li Wang

Jinglai Zhang

Mårten S.G. Ahlquist

Format Sitasi

APA MLA BibTeX

Wang, T., Zheng, D., An, B., Liu, Y., Ren, T., Ågren, H. et al. (2022). Dual-ionic imidazolium salts to promote synthesis of cyclic carbonates at atmospheric pressure. https://doi.org/10.1016/j.gee.2021.02.011

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Informasi Jurnal

Tahun Terbit: 2022
Sumber Database: DOAJ
DOI: 10.1016/j.gee.2021.02.011
Akses: Open Access ✓