DOAJ Open Access 2025

Simple synthesis of monocyclic pyrimidine-based energetic molecule with “amino–nitro–hydrazino” arrangement

Yuteng Cao Tianyu Jiang Ying Li Honglei Xia Yu Liu +1 lainnya

Abstrak

With the constant development of energetic materials, numerous explosive molecules have been synthesized, some of which feature competitive performances. However, energetic materials are directly oriented to application requirements. Therefore, more emphasis is gradually placed on route simplification and cost reduction while designing novel energetic molecules. In this work, monocyclic energetic compound 2,4-diamino-6-hydrazineyl-5-nitropyrimidine (3) was successfully obtained. This compound exhibits an alternating “amino–nitro–hydrazino” arrangement, featuring strong intramolecular hydrogen-bonding interaction. With cheap raw material, the whole reaction comprised only two steps, and exhibited simple post processing, only filtration. This novel energetic molecule possesses excellent mechanical security (IS > 40 J, FS > 360 N), acceptable thermal stability (Td = 225 °C), and good detonation parameters (Dv = 8470 m/s, P = 24.9 GPa), indicating that compound 3 may act as a candidate of insensitive explosives.

Topik & Kata Kunci

Explosives and pyrotechnics

Penulis (6)

Yuteng Cao

Tianyu Jiang

Ying Li

Honglei Xia

Yu Liu

Wenquan Zhang

Format Sitasi

APA MLA BibTeX

Cao, Y., Jiang, T., Li, Y., Xia, H., Liu, Y., Zhang, W. (2025). Simple synthesis of monocyclic pyrimidine-based energetic molecule with “amino–nitro–hydrazino” arrangement. https://doi.org/10.1016/j.fpc.2024.10.002

Akses Cepat

PDF tidak tersedia langsung

Cek di sumber asli →

Lihat di Sumber doi.org/10.1016/j.fpc.2024.10.002

Informasi Jurnal

Tahun Terbit: 2025
Sumber Database: DOAJ
DOI: 10.1016/j.fpc.2024.10.002
Akses: Open Access ✓