DOAJ Open Access 2022

Factors influencing the time dependence of porosity relaxation in cement during sorption: Experimental results from spatially resolved NMR

Magdalena Janota Ors Istok David A. Faux Peter J. McDonald

Abstrak

We use 1H nuclear magnetic resonance (NMR) methods to show that the relaxation time governing the redistribution of the gel-pore porosity in cement pastes during sorption depends, not surprisingly, on the dry state saturation and also, more surprisingly, on the sample size. The relaxation time is typically in the range 20 to 40 h for cylindrical samples 60 mm long dried to saturations between about 40 and 55%. It increases up to 200 h for samples dried to between 20 and 30% saturation. The times are all very much longer than for 1 mm samples. There is additional evidence to support the idea that the relaxation of hydrate inter-layer sized spaces occurs on at least two timescales, one of which is very much longer (months) than any of those listed above.

Topik & Kata Kunci

Penulis (4)

M

Magdalena Janota

O

Ors Istok

D

David A. Faux

P

Peter J. McDonald

Format Sitasi

Janota, M., Istok, O., Faux, D.A., McDonald, P.J. (2022). Factors influencing the time dependence of porosity relaxation in cement during sorption: Experimental results from spatially resolved NMR. https://doi.org/10.1016/j.cement.2022.100028

Akses Cepat

PDF tidak tersedia langsung

Cek di sumber asli →
Lihat di Sumber doi.org/10.1016/j.cement.2022.100028
Informasi Jurnal
Tahun Terbit
2022
Sumber Database
DOAJ
DOI
10.1016/j.cement.2022.100028
Akses
Open Access ✓