DOAJ Open Access 2013

Ion-molecule Interaction in Solutions of Lithium Tetrafluoroborate in Propylene Carbonate: an FTIR Vibrational Spectroscopic Study

Binbin Zhang Yuan Zhou Xiang Li Xiufeng Ren Hongen Nian +2 lainnya

Abstrak

FTIR (Fourier transformed infrared) spectra have been collected and analyzed for solutions of lithium tetrafluoroborate in propylene carbonate (PC). It has been shown that the carbonyl stretch, symmetric ring deformation stretch and ring deformation stretch bands for PC is very sensitive to the interaction between Li+ and the solvent molecule. Their half-peak breadth increases and bands split with the addition of LiBF4, indicating that a strong interaction exists between Li+ and PC molecule mainly through the oxygen group of C=O and ring position of PC.

Topik & Kata Kunci

Industrial electrochemistry Physical and theoretical chemistry

Penulis (7)

Binbin Zhang

Yuan Zhou

Xiang Li

Xiufeng Ren

Hongen Nian

Yue Shen

Qiang Yun

Format Sitasi

APA MLA BibTeX

Zhang, B., Zhou, Y., Li, X., Ren, X., Nian, H., Shen, Y. et al. (2013). Ion-molecule Interaction in Solutions of Lithium Tetrafluoroborate in Propylene Carbonate: an FTIR Vibrational Spectroscopic Study. https://doi.org/10.1016/S1452-3981(23)13303-7

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Informasi Jurnal

Tahun Terbit: 2013
Sumber Database: DOAJ
DOI: 10.1016/S1452-3981(23)13303-7
Akses: Open Access ✓