DOAJ Open Access 2014

Synthesis and Properties of Alternating Vinylene- Benzothiadiazole-Based Copolymers with Carbazole and Fluorene Derivatives for Photovoltaic Applications

Ali Mohammed Alsalme Abdulaziz Ali B. Alghamdi Ammar Abdul Ghani Q. Alhamdani Ahmed Iraqi

Abstrak

Three vinylene-benzothiadiazole based alternating copolymers with carbazole, 3,6-difluoro carbazole and fluorene were prepared via Suzuki coupling polymerisation in the presence of catalytic amounts of palladium (II) acetate Pd(OAc)2 and tri-ortho-tolylphosphine. P(o-tol)3. The molecular weights measured by gel permeation chromatography and copolymers were characterised by NMR, UV-Vis spectroscopy and cyclic voltammetry. The physical properties and their band gaps are discussed in relation with their donor units (carbazole and fluorene derivatives).

Penulis (4)

A

Ali Mohammed Alsalme

A

Abdulaziz Ali B. Alghamdi

A

Ammar Abdul Ghani Q. Alhamdani

A

Ahmed Iraqi

Format Sitasi

Alsalme, A.M., Alghamdi, A.A.B., Alhamdani, A.A.G.Q., Iraqi, A. (2014). Synthesis and Properties of Alternating Vinylene- Benzothiadiazole-Based Copolymers with Carbazole and Fluorene Derivatives for Photovoltaic Applications. https://doi.org/10.1016/S1452-3981(23)07902-6

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Informasi Jurnal
Tahun Terbit
2014
Sumber Database
DOAJ
DOI
10.1016/S1452-3981(23)07902-6
Akses
Open Access ✓