DOAJ Open Access 2023

Visible Light‐Driven Photocatalytic Transformation of Thiols to Disulfides in Water Catalyzed by Bi2S3

Fengyun Su Chunxia Yang Zhishuai Wang Wei Zhao Haiquan Xie +4 lainnya

Abstrak

Selective coupling of thiols to produce disulfides is one very important and classic type of coupling reactions. Herein, an environmentally friendly and practical photocatalytic system for oxidative coupling of thiols to disulfides is developed. With no sacrificial agent, no additional additive, just sole water as solvent, performed in air at room temperature, excellent conversions of thiols and excellent selectivities of disulfides are obtained using a cheap and simple semiconductor material of bismuth sulfide (Bi2S3) under blue LED illumination. Excellent conversions and selectivities for coupling of thiols to produce disulfides are obtained, and the system is reusable. The as‐prepared photocatalyst is adequately characterized and the mechanism of photocatalytic reaction is discussed deeply.

Topik & Kata Kunci

Environmental technology. Sanitary engineering Renewable energy sources

Penulis (9)

Fengyun Su

Chunxia Yang

Zhishuai Wang

Wei Zhao

Haiquan Xie

Sheng Zhang

Xiaoli Jin

Qunzeng Huang

Liqun Ye

Format Sitasi

APA MLA BibTeX

Su, F., Yang, C., Wang, Z., Zhao, W., Xie, H., Zhang, S. et al. (2023). Visible Light‐Driven Photocatalytic Transformation of Thiols to Disulfides in Water Catalyzed by Bi2S3. https://doi.org/10.1002/aesr.202300071

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Informasi Jurnal

Tahun Terbit: 2023
Sumber Database: DOAJ
DOI: 10.1002/aesr.202300071
Akses: Open Access ✓