Interactions Enhance Ramp Reversal Memory in Locally Phase Separated Materials

Abstract The ramp‐reversal memory (RRM) effect in metal–insulator transition metal oxides (TMOs), a non‐volatile resistance change induced by repeated temperature cycling, has attracted considerable interest in neuromorphic computing and non‐volatile memory devices. Our previous defect motion model successfully explained RRM in vanadium dioxide (VO2), capturing observed critical temperature shifts and memory accumulation throughout the sample. However, this approach lacked interactions between metallic and insulating domains. Here, we extend our model by combining a correlated Random Field Ising Model with defect diffusion‐segregation, enabling accurate hysteresis modeling while predicting the relationship between RRM and domain interactions. Our simulations demonstrate that the maximum RRM occurs when the turnaround temperature approaches the inflection point. This peak in RRM vs. turnaround temperature is consistent with prior transport measurements, as well as our own optical measurements reported here. Significantly, we find that increasing nearest‐neighbor interactions enhances the maximum memory effect, thus providing a clear mechanism for optimizing RRM performance. Since our model employs minimal assumptions, we predict that RRM should be a widespread phenomenon in materials exhibiting patterned phase coexistence of electronic domains. This work not only advances fundamental understanding of memory behavior in TMOs but also establishes a much‐needed theoretical framework for optimizing device applications.