Superconductivity in Ternary Mg4Pd7As6
Abstrak
Abstract The synthesis and characterization of a new compound Mg4Pd7As6, which is found to be a superconductor with Tc = 5.45 K is reported. Powder X‐ray diffraction confirms the U4Re7Si6 structure (space group Im‐3m, no. 229) with the lattice parameter a = 8.2572(1) Å. Magnetization, specific heat, and electrical resistivity measurements indicate that it is a moderate‐coupling (λ = 0.72) type‐II superconductor. The electronic and phonon structures are calculated, highlighting the importance of antibonding Pd–As interactions in determining the properties of this material. The calculated electron–phonon coupling parameter λ = 0.76 agrees very well with the experimental finding, which confirms the conventional pairing mechanism in Mg4Pd7As6.
Topik & Kata Kunci
Penulis (5)
Hanna Świątek
Sylwia Gutowska
Michał J. Winiarski
Bartlomiej Wiendlocha
Tomasz Klimczuk
Akses Cepat
- Tahun Terbit
- 2025
- Sumber Database
- DOAJ
- DOI
- 10.1002/aelm.202400284
- Akses
- Open Access ✓