DOAJ Open Access 2023

Unravelling the Multiple Synergies in MOF/CMP Supramolecular Heterojunction for Enhanced Artificial Photosynthesis

Bo Chen Wanru Chen Miao Wang Chuang Peng

Abstrak

Abstract Metal–organic framework (MOF) and conjugated microporous polymers (CMP) are two groups of supramolecular structures with potential applications for artificial photosynthesis though their catalytic activities are yet to be improved. A MOF/CMP hybrid photocatalyst NU@FNBZ with markedly higher catalytic activity for CO2 reduction to CO is hereby reported. The hybrid catalyst benefits from the high CO2 adsorption capacity of NU and the high visible light response of FNBZ. Moreover, the covalent bonding facilitates the formation of type II heterojunction that allows electron transfer from FNBZ to NU, leading to improved catalytic activity in the electron rich NU and enhanced CO2 adsorption in the electron depleted FNBZ. This work manifests that multiple synergy effects can be achieved by rational design of hybrid supramolecular photocatalysts.

Topik & Kata Kunci

Physics Technology

Penulis (4)

Bo Chen

Wanru Chen

Miao Wang

Chuang Peng

Format Sitasi

APA MLA BibTeX

Chen, B., Chen, W., Wang, M., Peng, C. (2023). Unravelling the Multiple Synergies in MOF/CMP Supramolecular Heterojunction for Enhanced Artificial Photosynthesis. https://doi.org/10.1002/admi.202201971

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Informasi Jurnal

Tahun Terbit: 2023
Sumber Database: DOAJ
DOI: 10.1002/admi.202201971
Akses: Open Access ✓