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CrossRef Open Access 1989 28 sitasi

Notizen: Darstellung und Kristallstruktur von Cs<sub>4</sub>Sn<sub>2</sub>Se<sub>6</sub> / Preparation and Crystal Structure of Cs<sub>4</sub>Sn<sub>2</sub>Se<sub>6</sub>

W. S. Sheldrick H. G. Braunbeck
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Abstrak

The selenostannate(IV) Cs4Sn2Se6 has been prepared by methanolothermal reaction of Cs2CO3 with SnSe2 at 160°C and 13 bar. The [Sn2Se6]4— anions contain two edge-bridged SnSe4 tetrahedra and display crystallographic C2h symmetry. The bridging Sn—Se distances of 2.587(1) are markedly longer than the terminal Sn—Se distances of 2.447(1) and 2.452(2) Å.

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W

W. S. Sheldrick

H

H. G. Braunbeck

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Sheldrick, W.S., Braunbeck, H.G. (1989). Notizen: Darstellung und Kristallstruktur von Cs<sub>4</sub>Sn<sub>2</sub>Se<sub>6</sub> / Preparation and Crystal Structure of Cs<sub>4</sub>Sn<sub>2</sub>Se<sub>6</sub>. https://doi.org/10.1515/znb-1989-0720

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Informasi Jurnal
Tahun Terbit
1989
Bahasa
en
Total Sitasi
28×
Sumber Database
CrossRef
DOI
10.1515/znb-1989-0720
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Open Access ✓