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CrossRef Open Access 1983 10 sitasi

Osmiumisonitril-Komplexe mit Os-H-, Os-CH<sub>3</sub>- und Os-Au-Bindungen [1] / Osmiumisonitrile Complexes Containing Os-H. Os-CH<sub>3</sub> and Os-Au Bonds [1]

H. Werner R. Weinand
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Abstrak

Abstract The complexes C6H6Os(PMe3)CNR (R = Me, t-Bu, p-Tol, Ph) are prepared from [C6H6OsI(PMe3)CNR]PF6 and NaC10H8. They behave as metal bases and react with NH4PF6, CH3I and ClAuPPh3 to form salts of the corresponding cations [C6H6OsX(PMe3)CNR]+ where X is H, CH3 and AuPPh3, respectively. The reactions of [C6H6OsX(PMe3)CNR]PF6 (X = I, H, CH3) with excess PMe3 lead to displacement of the benzene ring and formation of the complexes trans-[OsX(CNR)(PMe3)4]PF6.

Penulis (2)

H

H. Werner

R

R. Weinand

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Werner, H., Weinand, R. (1983). Osmiumisonitril-Komplexe mit Os-H-, Os-CH<sub>3</sub>- und Os-Au-Bindungen [1] / Osmiumisonitrile Complexes Containing Os-H. Os-CH<sub>3</sub> and Os-Au Bonds [1]. https://doi.org/10.1515/znb-1983-1133

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Informasi Jurnal
Tahun Terbit
1983
Bahasa
en
Total Sitasi
10×
Sumber Database
CrossRef
DOI
10.1515/znb-1983-1133
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Open Access ✓