CrossRef
Open Access
1983
19 sitasi
Cs<sub>6</sub>Ga<sub>2</sub>Se<sub>6</sub>, ein ternäres Selenogallat(III) mit isolierten [Ga<sub>2</sub>Se<sub>6</sub>]<sup>6-</sup>-Ionen/Cs<sub>6</sub>Ga<sub>2</sub>Se<sub>6</sub>, a Ternary Selenogallate(III) with Isolated [Ga<sub>2</sub>Se<sub>6</sub>]<sup>6-</sup> Ions
Hans-Jörg Deiseroth
Han Fu-Son
Abstrak
Abstract Cs6Ga2Se6 can be prepared from mixtures of Cs2Se and Ga2Se3. The transparent single crystals of the moisture sensitive compound (m.p. 685 °C) crystallize in the monoclinic system with a = 848.0(5), b = 1364.4(5), c = 1111.5(5) pm, β = 126.22(5)° (T = -150 °C, Z = 2, space group P21/c). The gallium atoms pairwisely occupy selected tetrahedral holes between layers formed by the cesium and selenium ions. This structural principle leads to the formation of double tetrahedral isolated [Ga2Se6] 6- ions.
Penulis (2)
H
Hans-Jörg Deiseroth
H
Han Fu-Son
Format Sitasi
Deiseroth, H., Fu-Son, H. (1983). Cs<sub>6</sub>Ga<sub>2</sub>Se<sub>6</sub>, ein ternäres Selenogallat(III) mit isolierten [Ga<sub>2</sub>Se<sub>6</sub>]<sup>6-</sup>-Ionen/Cs<sub>6</sub>Ga<sub>2</sub>Se<sub>6</sub>, a Ternary Selenogallate(III) with Isolated [Ga<sub>2</sub>Se<sub>6</sub>]<sup>6-</sup> Ions. https://doi.org/10.1515/znb-1983-0212
Akses Cepat
Informasi Jurnal
- Tahun Terbit
- 1983
- Bahasa
- en
- Total Sitasi
- 19×
- Sumber Database
- CrossRef
- DOI
- 10.1515/znb-1983-0212
- Akses
- Open Access ✓