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CrossRef Open Access 1976 37 sitasi

Die Struktur von Ph-P[C<sub>5</sub>H<sub>5</sub>(CO)<sub>2</sub>MnFe<sub>2</sub>(CO)<sub>6</sub>]. Ein Komplex mit einem verbrückenden μ<sup>3</sup>-Ph-P-Liganden.

G. Huttner A. Frank G. Mohr
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Abstrak

The title compound, which may be prepared from C5H5(CO)2Mn—P(Ph)Cl2 and Fe2(CO)9 crystallizes in the monoclinic space group C 2/c with a = 1579(2), b = 1592(2), c = 1790(3) pm, β = 97.2(1)°, Z = 8. The structure was solved by direct methods. Full matrix refinement led to R1= 0.066. The compound contains a threemembered metallocycle with two iron and one manganes atoms. Each iron atom bears three terminal carbonyl groups; the two CO-ligands of the C5H5Mn(CO)2 fragment form unsymmetrical bridges with the two iron atoms. The metal triangel is capped by a Ph—P group with a triply bridging phosphorus atom.

Penulis (3)

G

G. Huttner

A

A. Frank

G

G. Mohr

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Huttner, G., Frank, A., Mohr, G. (1976). Die Struktur von Ph-P[C<sub>5</sub>H<sub>5</sub>(CO)<sub>2</sub>MnFe<sub>2</sub>(CO)<sub>6</sub>]. Ein Komplex mit einem verbrückenden μ<sup>3</sup>-Ph-P-Liganden.. https://doi.org/10.1515/znb-1976-0901

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Informasi Jurnal
Tahun Terbit
1976
Bahasa
en
Total Sitasi
37×
Sumber Database
CrossRef
DOI
10.1515/znb-1976-0901
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Open Access ✓