CrossRef 1987 62 sitasi

Adiabatic decomposition of mass-selected alkali clusters

C. Bréchignac Ph. Cahuzac J.-Ph. Roux D. Pavolini F. Spiegelmann

Lihat Sumber DOI

Abstrak

The decomposition of metastable photoionized mass-selected alkali clusters is investigated using a tandem time-of-flight spectrometer. Na+n and K+n are found to decompose mainly by the evaporation of either a single neutral atom or a neutral dimer in a time scale of about 10 μs. The predominant fragmentation channels are found to follow the adiabatic dissociation channels associated with the lowest energies accordingly to our CI calculations. In the light of our experimental and theoretical results a comparison between the different calculations of the absolute atomization energies available in the literature is presented.

Penulis (5)

C. Bréchignac

Ph. Cahuzac

J.-Ph. Roux

D. Pavolini

F. Spiegelmann

Format Sitasi

APA MLA BibTeX

Bréchignac, C., Cahuzac, P., Roux, J., Pavolini, D., Spiegelmann, F. (1987). Adiabatic decomposition of mass-selected alkali clusters. https://doi.org/10.1063/1.453544

Akses Cepat

Lihat di Sumber doi.org/10.1063/1.453544

Informasi Jurnal

Tahun Terbit: 1987
Bahasa: en
Total Sitasi: 62×
Sumber Database: CrossRef
DOI: 10.1063/1.453544
Akses: Terbatas