CrossRef Open Access 2022 7 sitasi

Direction of theoretical and experimental investigation into the mechanism of n-HA/Si-PA-SC@Ag as a bio-based heterogeneous catalyst in the reduction reactions

Zohreh Nouripour Sisakhti Masoume Malmir Masoumeh Bagheri Bisafar Majid M. Heravi Tayebeh Hosseinnejad

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Abstrak

AbstractIn the present study, a natural-based heterogeneous catalyst is synthesized. For this purpose, nano-hydroxyapatite (n-HA) is prepared, silica-modified and functionalized with phthalimide. Finally, Ag2+was immobilized onto n-HA/Si-PA-SC and reduced to Ag nanoparticles byBellis perennisflowers extract. n-HA/Si-PA-SC@Ag characterized by TGA, FTIR, SEM/EDX, XRD, TEM, BET and ICP-AES techniques. Moreover, metal–ligand interactions in n-HA/Si-PA-SC@Ag complex models were assessed to make a quantitative representation for the immobilization behavior of Ag NPs on the surface of n-HA/Si-PA-SC through quantum chemistry computations. Furthermore, the performance of n-HA/Si-PA-SC@Ag was studied in the nitroarene, methylene blue and congo red reductions. Finally, the recyclability study as well as Ag-leaching verified that, n-HA/Si-PA-SC@Ag was stable and reused-up to four times without losing its activity.

Penulis (5)

Zohreh Nouripour Sisakhti

Masoume Malmir

Masoumeh Bagheri Bisafar

Majid M. Heravi

Tayebeh Hosseinnejad

Format Sitasi

APA MLA BibTeX

Sisakhti, Z.N., Malmir, M., Bisafar, M.B., Heravi, M.M., Hosseinnejad, T. (2022). Direction of theoretical and experimental investigation into the mechanism of n-HA/Si-PA-SC@Ag as a bio-based heterogeneous catalyst in the reduction reactions. https://doi.org/10.1038/s41598-022-26200-3

Akses Cepat

Lihat di Sumber doi.org/10.1038/s41598-022-26200-3

Informasi Jurnal

Tahun Terbit: 2022
Bahasa: en
Total Sitasi: 7×
Sumber Database: CrossRef
DOI: 10.1038/s41598-022-26200-3
Akses: Open Access ✓