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CrossRef Open Access 2018 4 sitasi

Synthesis and Crystal Structure of Cs<sub>2</sub>U<sub>2</sub>(P<sub>2</sub>Se<sub>9</sub>)(Se<sub>2</sub>)<sub>2</sub>

Adel Mesbah Jai Prakash Jessica C. Beard Sébastien Lebègue James A. Ibers
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Abstrak

Black single crystals of Cs2U2(P2Se9)(Se2)2 were synthesized at 1023 K by a solid‐state reaction. Its structure was determined by single‐crystal X‐ray diffraction methods. The compound is isostructural with Rb2U2(P2Se9)(Se2)2 and Cs2Th2(P2Se9)(Se2)2 compounds, and crystallizes in the orthorhombic space group Pbca. Cs2U2(P2Se9)(Se2)2 displays a three‐dimensional structure comprising USe9 polyhedra connected via the Se22– and P2Se9 species with channels filled by Cs atoms. From electronic structure calculations the compound is found to be a metal with a ferromagnetic arrangement of the magnetic moments.

Penulis (5)

A

Adel Mesbah

J

Jai Prakash

J

Jessica C. Beard

S

Sébastien Lebègue

J

James A. Ibers

Format Sitasi

APA MLA BibTeX
Mesbah, A., Prakash, J., Beard, J.C., Lebègue, S., Ibers, J.A. (2018). Synthesis and Crystal Structure of Cs<sub>2</sub>U<sub>2</sub>(P<sub>2</sub>Se<sub>9</sub>)(Se<sub>2</sub>)<sub>2</sub>. https://doi.org/10.1002/zaac.201800263

Akses Cepat

Lihat di Sumber doi.org/10.1002/zaac.201800263
Informasi Jurnal
Tahun Terbit
2018
Bahasa
en
Total Sitasi
4×
Sumber Database
CrossRef
DOI
10.1002/zaac.201800263
Akses
Open Access ✓