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CrossRef Open Access 2009 13 sitasi

Die Suboxometallate A<sub>9</sub>MO<sub>4</sub> (A = Rb, Cs; M = Al, Ga, In, Fe, Sc) 

Constantin Hoch Johannes Bender Andreas Wohlfarth Arndt Simon
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AbstractSingle crystals of the suboxometallates A9MO4 (A = Rb, Cs;M = Al, Ga, Fe, Sc) were prepared by reaction of stoichiometric mixtures of M2O3 with alkali metals and their oxides A2O. They crystallize in the tetragonal Cs9InO4 structure type (space group I4/mcm) and contain ortho‐oxometallate(III) anions in a metallic matrix. Cesium can be partially substituted by rubidium, as shown for phases of arbitrary compositions (RbxCs1–x)Cs8GaO4 (x = 0.57) and (RbxCs1–x)Cs8InO4 (x = 0.87). The substitution leads to statistical occupation of one crystallographic position. The same holds for substitutions of M, as in Cs9(AlxIn1–x)O4 (x = 0.51) and Cs9(ScxIn1–x)O4 (x = 0.68).

Penulis (4)

C

Constantin Hoch

J

Johannes Bender

A

Andreas Wohlfarth

A

Arndt Simon

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Hoch, C., Bender, J., Wohlfarth, A., Simon, A. (2009). Die Suboxometallate A<sub>9</sub>MO<sub>4</sub> (A = Rb, Cs; M = Al, Ga, In, Fe, Sc) . https://doi.org/10.1002/zaac.200900193

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Tahun Terbit
2009
Bahasa
en
Total Sitasi
13×
Sumber Database
CrossRef
DOI
10.1002/zaac.200900193
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Open Access ✓