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CrossRef Open Access 2005 15 sitasi

Methanolothermal Synthesis and Structures of the Quaternary Group 14 – Group 15 Cesium Selenidometalates Cs<sub>3</sub>AsGeSe<sub>5</sub> and Cs<sub>4</sub>Ge<sub>2</sub>Se<sub>6</sub>

Tobias van Almsick William S. Sheldrick
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AbstractCs3AsGeSe5 and Cs4Ge2Se6 can be prepared by methanolothermal reaction of elemental As, Ge and Se with Cs2CO3 at 190 °C. The former quaternary phase contains zweier $^{1}_{\infty}$[{AsGeSe5}3−] chains consisting of corner‐bridged GeSe4 tetrahedra and AsSe3 pyramids and represents the first GeIV‐AsIII chalcogenidometalate. Cs4Ge2Se6 exhibits discrete [Ge2Se6]4− anions formed by two edge‐sharing GeSe4 tetrahedra.

Penulis (2)

T

Tobias van Almsick

W

William S. Sheldrick

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Almsick, T.v., Sheldrick, W.S. (2005). Methanolothermal Synthesis and Structures of the Quaternary Group 14 – Group 15 Cesium Selenidometalates Cs<sub>3</sub>AsGeSe<sub>5</sub> and Cs<sub>4</sub>Ge<sub>2</sub>Se<sub>6</sub>. https://doi.org/10.1002/zaac.200500136

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Informasi Jurnal
Tahun Terbit
2005
Bahasa
en
Total Sitasi
15×
Sumber Database
CrossRef
DOI
10.1002/zaac.200500136
Akses
Open Access ✓