CrossRef Open Access 2005 16 sitasi

Divalent Titanium: The Halides ATiX<sub>3</sub> (A = K, Rb, Cs; X = Cl, Br, I)

Liesbet Jongen Thomas Gloger Jan Beekhuizen Gerd Meyer

Abstrak

AbstractWithin the 3×3 library of ternary alkali halides of titanium(II), ATiX3 (A = K, Rb, Cs; X = Cl, Br, I), five compounds were synthesized by conproportionation reactions. Single crystals were grown and the structures determined by single‐crystal X‐ray techniques. The halides ATiX3 crystallize either with the so‐called hexagonal perovskite type structure (CsNiCl3, 2H), or with the so‐called KNiCl3‐type of structure. This latter type allows two structural degrees of freedom. First, a shift of the colums of face‐sharing [TiCl6] octahedra against each other and, secondly, a rotation of these colums relative to each other. With these degrees of freedom, individual coordination spheres are designed for the alkali‐metal cations A+.

Penulis (4)

Liesbet Jongen

Thomas Gloger

Jan Beekhuizen

Gerd Meyer

Format Sitasi

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Jongen, L., Gloger, T., Beekhuizen, J., Meyer, G. (2005). Divalent Titanium: The Halides ATiX<sub>3</sub> (A = K, Rb, Cs; X = Cl, Br, I). https://doi.org/10.1002/zaac.200400464

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Informasi Jurnal

Tahun Terbit: 2005
Bahasa: en
Total Sitasi: 16×
Sumber Database: CrossRef
DOI: 10.1002/zaac.200400464
Akses: Open Access ✓