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CrossRef Open Access 1997 8 sitasi

Synthese und Kristallstruktur von Cs<sub>3</sub>Y<sub>7</sub>Se<sub>12</sub>

Matthias Folchnandt Thomas Schleid
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Synthesis and Crystal Structure of Cs3Y7Se12The oxidation of yttrium metal with selenium in the presence of CsCl (7 d, 700°C, evacuated silicia tubes) results in the formation of pale yellow, lath‐shaped single crystals of Cs3Y7Se12. The crystal structure (orthorhombic, Pnnm, Z = 2, a = 1272.8(3), b = 2627.7(5), c = 413.32(8) pm) consists of edge‐ and vertex‐connected [YSe6] octahedra forming a rocksalt‐related network [Y7Se12]3−. One‐dimensional infinite channels along [001], apt to take up extra cations, provide coordination numbers of 6 and 7 + 1, respectively, for two crystallographically different Cs+.

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M

Matthias Folchnandt

T

Thomas Schleid

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Folchnandt, M., Schleid, T. (1997). Synthese und Kristallstruktur von Cs<sub>3</sub>Y<sub>7</sub>Se<sub>12</sub>. https://doi.org/10.1002/zaac.19976231005

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Tahun Terbit
1997
Bahasa
en
Total Sitasi
8×
Sumber Database
CrossRef
DOI
10.1002/zaac.19976231005
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Open Access ✓