CrossRef Open Access 1973 27 sitasi

Enthalpies of mixing of charge unsymmetrical binary fused salt systems: ZnX<sub>2</sub>AX (A = Li, Cs, Ag; X = Cl, Br)

G. N. Papatheodorou O. J. Kleppa

Abstrak

AbstractThe enthalpies of mixing (ΔHM) of the following binary fused‐salt mixtures have been determined calorimetrically: ZnCl2CsCl, ZnCl2LiCl, ZnCl2AgCl, ZnBr2CsBr, ZnBr2LiBr at 665°C; ZnCl2CsCl, ZnCl2AgCl, and ZnCl2ZnBr2 at 495°C. The results are discussed with respect to the following points: (1) Comparison with the transition metal chloride‐alkali chloride systems, (2) “complexing” in the mixture. (3) effect of the network‐like structure of pure ZnX2, and (4) effect of temperature.

Penulis (2)

G. N. Papatheodorou

O. J. Kleppa

Format Sitasi

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Papatheodorou, G.N., Kleppa, O.J. (1973). Enthalpies of mixing of charge unsymmetrical binary fused salt systems: ZnX<sub>2</sub>AX (A = Li, Cs, Ag; X = Cl, Br). https://doi.org/10.1002/zaac.19734010203

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Informasi Jurnal

Tahun Terbit: 1973
Bahasa: en
Total Sitasi: 27×
Sumber Database: CrossRef
DOI: 10.1002/zaac.19734010203
Akses: Open Access ✓