CrossRef
Open Access
2017
17 sitasi
[DMAPTs] <sup>+</sup> Cl <sup>−</sup> : A Promising Versatile Regioselective Tosyl Transfer Reagent
Chiranjeevi Donthulachitti
Sridhar Reddy Kothakapu
Ravi Kumar Shekunti
Chandra Kiran Neella
Abstrak
Abstract Regioselective monotosylation, for the first time on 2,4‐ syn & 2,4‐ anti configured ene‐tetrols and on diols & triols was achieved in excellent yields and selectivity by employing [DMAPTs] + Cl − , 1 . We also proposed and developed operational flexible preferential regio‐complimentary tosylation of cis ‐1,2‐diol moiety of pyranosides by employing 1 . Further NMR correlation for unambiguous structure determination of regioselectivity and also preferred conformations of these pyranosides were established.
Penulis (4)
C
Chiranjeevi Donthulachitti
S
Sridhar Reddy Kothakapu
R
Ravi Kumar Shekunti
C
Chandra Kiran Neella
Akses Cepat
Informasi Jurnal
- Tahun Terbit
- 2017
- Bahasa
- en
- Total Sitasi
- 17×
- Sumber Database
- CrossRef
- DOI
- 10.1002/slct.201700675
- Akses
- Open Access ✓