CrossRef Open Access 2017 17 sitasi

[DMAPTs] <sup>+</sup> Cl <sup>−</sup> : A Promising Versatile Regioselective Tosyl Transfer Reagent

Chiranjeevi Donthulachitti Sridhar Reddy Kothakapu Ravi Kumar Shekunti Chandra Kiran Neella

Abstrak

Abstract Regioselective monotosylation, for the first time on 2,4‐ syn & 2,4‐ anti configured ene‐tetrols and on diols & triols was achieved in excellent yields and selectivity by employing [DMAPTs] + Cl − , 1 . We also proposed and developed operational flexible preferential regio‐complimentary tosylation of cis ‐1,2‐diol moiety of pyranosides by employing 1 . Further NMR correlation for unambiguous structure determination of regioselectivity and also preferred conformations of these pyranosides were established.

Penulis (4)

C

Chiranjeevi Donthulachitti

S

Sridhar Reddy Kothakapu

R

Ravi Kumar Shekunti

C

Chandra Kiran Neella

Format Sitasi

Donthulachitti, C., Kothakapu, S.R., Shekunti, R.K., Neella, C.K. (2017). [DMAPTs] <sup>+</sup> Cl <sup>−</sup> : A Promising Versatile Regioselective Tosyl Transfer Reagent. https://doi.org/10.1002/slct.201700675

Akses Cepat

Lihat di Sumber doi.org/10.1002/slct.201700675
Informasi Jurnal
Tahun Terbit
2017
Bahasa
en
Total Sitasi
17×
Sumber Database
CrossRef
DOI
10.1002/slct.201700675
Akses
Open Access ✓