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CrossRef Open Access 1973 3 sitasi

Diamagnetism and Superexchange Electron Interaction in Cs<sub>2</sub>Sb (IV) Cl<sub>6</sub>, Semiconducting Crystals

G. V. Ionova S. P. Ionov E. F. Makarov A. Yu. Aleksandrov
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Abstrak

AbstractCrystals of Cs2Sb SbCl6Sb are diamagnetic and have a cubic structure of the antifluorite type. These facts may be explained either in terms of statistical disorder between Sb(III) and Sb(V) or in terms of electron exchange between SbCl and SbCl. A calculation is presented of the exchange interaction between the nearest SbCl complexes. The exchange integral £ is taken in form £ = (Es − Et)/2 where Es and Et are energies of singlet and triplet states. It is established that CI atoms mainly contribute to the exchange interaction. Sign and value of the exchange integral correspond to an antiferromagnetically ordered state in Cs2SbCl6 at room temperature.

Penulis (4)

G

G. V. Ionova

S

S. P. Ionov

E

E. F. Makarov

A

A. Yu. Aleksandrov

Format Sitasi

APA MLA BibTeX
Ionova, G.V., Ionov, S.P., Makarov, E.F., Aleksandrov, A.Y. (1973). Diamagnetism and Superexchange Electron Interaction in Cs<sub>2</sub>Sb (IV) Cl<sub>6</sub>, Semiconducting Crystals. https://doi.org/10.1002/pssb.2220560223

Akses Cepat

Lihat di Sumber doi.org/10.1002/pssb.2220560223
Informasi Jurnal
Tahun Terbit
1973
Bahasa
en
Total Sitasi
3×
Sumber Database
CrossRef
DOI
10.1002/pssb.2220560223
Akses
Open Access ✓