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CrossRef Open Access 1990 22 sitasi

Anions Isosteric with CO in Cs<sub>5</sub>SiP<sub>3</sub>, Cs<sub>5</sub>SiAs<sub>3</sub>, Cs<sub>5</sub>GeP<sub>3</sub>, and Cs<sub>5</sub>GeAs<sub>3</sub>

Brigitte Eisenmann Jürgen Klein Mehmet Somer
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Abstrak

Planar, isolated anions SiP, SiAs, GeP and GeAs are present in the crystals of the dark, shiny metallic title compounds (Zintl phases). The 24‐valence electron units are the first examples of CO ‐isosteric anions in which central atoms and ligands belong to higher periods. Bond orders (after Pauling) of 1.22, 1.28, 1.12 and 1.26, respectively, can be derived from the measured bond lengths.

Penulis (3)

B

Brigitte Eisenmann

J

Jürgen Klein

M

Mehmet Somer

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Eisenmann, B., Klein, J., Somer, M. (1990). Anions Isosteric with CO in Cs<sub>5</sub>SiP<sub>3</sub>, Cs<sub>5</sub>SiAs<sub>3</sub>, Cs<sub>5</sub>GeP<sub>3</sub>, and Cs<sub>5</sub>GeAs<sub>3</sub>. https://doi.org/10.1002/anie.199000871

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Informasi Jurnal
Tahun Terbit
1990
Bahasa
en
Total Sitasi
22×
Sumber Database
CrossRef
DOI
10.1002/anie.199000871
Akses
Open Access ✓