arXiv
Open Access
2025
Nonadiabatic corrections to electric quadrupole transition rates in H$_2$
Krzysztof Pachucki
Michał Siłkowski
Abstrak
We derive formulas and perform calculations of nonadiabatic corrections to rates of electric quadrupole transitions in the hydrogen molecule. These corrections can be represented in terms of the quadrupole moment curve $D^{(1)}(R)$, similarly to the Born-Oppenheimer one, $D^{(0)}(R)$, derived originally by Wolniewicz. Numerical results change E2 transition rates for the fundamental band by as much as 0.4 - 12\% depending on rotational quantum numbers.
Topik & Kata Kunci
Penulis (2)
K
Krzysztof Pachucki
M
Michał Siłkowski
Akses Cepat
Informasi Jurnal
- Tahun Terbit
- 2025
- Bahasa
- en
- Sumber Database
- arXiv
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- Open Access ✓