Using wetting and ultrasonic waves to extract oil from oil/water mixtures

Oil and water placed atop of a solid surface respond differently to a MHz-level surface acoustic wave (SAW) propagating in the solid due to their different surface wetting properties. We observe that, under SAW excitation, oil films, whether non-organic silicon oil or organic sunflower oil, are extracted continuously from sessile drops, comprising emulsions of the oil in question in a solution of water and surfactants. The mechanism responsible for the extraction of oil from the mixtures is the acoustowetting phenomenon: the low surface tension oil phase leaves the mixture in the form of 'fingers' that, away from the drop, spread opposite the path of the SAW. The high surface tension water phase remains at rest. Increasing either the SAW intensity or the oil content in the mixture enhances the rate at which oil leaves the emulsion. We further observe acoustic-capillary flow instabilities at the free surface of the oil film and the formation of spatial gradients in the emulsion oil-concentrations in the presence of SAW. Our study suggests the potential for using SAW for heterogeneous removal of oil from oil-in-water mixtures to complement current phase separation methods.