arXiv Open Access 2023

Trade-offs between number fluctuations and response in nonequilibrium chemical reaction networks

Hyun-Myung Chun Jordan M. Horowitz

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Abstrak

We study the response of chemical reaction networks driven far from equilibrium to logarithmic perturbations of reaction rates. The response of the mean number of a chemical species is observed to be quantitively limited by number fluctuations as well as the maximum thermodynamic driving force. We prove these trade-offs for linear chemical reaction networks and a class of nonlinear chemical reaction networks with a single chemical species. Numerical results for several model systems support the conclusion that these trade-offs continue to hold for a broad class of chemical reaction networks, though their precise form appears to depend sensitively on the deficiency of the network.

Topik & Kata Kunci

cond-mat.stat-mech physics.chem-ph

Penulis (2)

Hyun-Myung Chun

Jordan M. Horowitz

Format Sitasi

APA MLA BibTeX

Chun, H., Horowitz, J.M. (2023). Trade-offs between number fluctuations and response in nonequilibrium chemical reaction networks. https://arxiv.org/abs/2304.04961

Akses Cepat

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Informasi Jurnal

Tahun Terbit: 2023
Bahasa: en
Sumber Database: arXiv
Akses: Open Access ✓