Upper limit on the fraction of alien civilizations that develop communication technology

We re-examine the likelihood for alien civilizations to develop communication technology on the basis of the general assumption that life elsewhere could have a non-carbon chemical foundation. We particularized the discussion to a complex silicon-based biochemistry in a nitrogen solvent, and elaborate on the environment in which such a chemistry is feasible, and if so, on what scales. More concretely, we determine the region outside the habitable zone where such organisms can grow and flourish and after that we study how our findings impact the recently derived upper limit on the fraction of living intelligent species that develop communication technology $\langle ξ_{\rm biotec} \rangle$. We also compare this new restriction on $\langle ξ_{\rm biotec} \rangle$ with that resulting from the extension of the habitable zone to accommodate subsurface exolife, originating in planets with subsurface (water) oceans.