arXiv Open Access 2013

Molecular kinetics of solid and liquid CHCl$_3$

Nirvana B. Caballero Mariano Zuriaga Marcelo A. Carignano Pablo Serra

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Abstrak

We present a detailed analysis of the molecular kinetics of CHCl$_3$ in a range of temperatures covering the solid and liquid phases. Using nuclear quadrupolar resonance we determine the relaxation times for the molecular rotations in solid at pre-melting conditions. Molecular dynamics simulations are used to characterize the rotational dynamics in the solid and liquid phases and to study the local structure of the liquid in terms of the molecular relative orientations. We find that in the pre-melting regime the molecules rotate about the C-H bond, but the rotations are isotropic in the liquid, even at supercooled conditions.

Topik & Kata Kunci

physics.chem-ph

Penulis (4)

Nirvana B. Caballero

Mariano Zuriaga

Marcelo A. Carignano

Pablo Serra

Format Sitasi

APA MLA BibTeX

Caballero, N.B., Zuriaga, M., Carignano, M.A., Serra, P. (2013). Molecular kinetics of solid and liquid CHCl$_3$. https://arxiv.org/abs/1308.5931

Akses Cepat

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Informasi Jurnal

Tahun Terbit: 2013
Bahasa: en
Sumber Database: arXiv
Akses: Open Access ✓